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CATALYTIC
MATERIALS
The missing ingredient to overcoming years of technological catalytic
barriers!
Sawyer Technical Materials, LLC has recently adapted our hydrothermal crystal
growth technology to the synthesis of a variety of materials used in catalysis.
This technology can be uniquely applied to the production of materials enabling
the targeted control of the type, location, density, and accessibility of
catalytic sites within a given material to a degree very difficult, if not
impossible, to achieve by other synthesis techniques. These product advancements
are all uniquely application-specific and will require a close collaboration
with clients. We have already successfully produced a wide variety of
inorganic catalytic materials using this technique. Our recent spectacular
successes in commercial development of catalytic materials include:
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High-purity
a -alumina supports with tailored surface area, pore volume and pore
size distributions
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Nanosized zinc oxide powders with controlled morphology and superior defect
structure
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Zeolites L, NaP1, beta, mordenite, ZSM-5, and others
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High purity
a -alumina powders
with a broad variety of sizes, morphologies (incl. fibers),
and chemical compositions (dopants)
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a -alumina/ transition aluminas compositesSpecialty aluminas, i.e.
a -alumina/boehmite composite powders
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Wide range of metal oxides and
metal aluminates (ZnAl2O4, etc)
We have capabilities to grow single crystals,
powders, fibers, monolithic ceramic bodies, and coatings of most of
the inorganic materials, primarily oxides. Combinatorial studies
under industrial conditions and doping elements into the lattice of
a carrier (alumina, silica, etc.) are two specific strengths we
strategically utilize for catalytic materials research and
development.
Sawyer is validating its new
materials technology via commercial, academic and research contacts
throughout the catalyst community. By leveraging existing
capabilities, development has been done at commercial scale and
substantial manufacturing capacity is already in place; thus
minimizing scale-up and ramp-up costs as well as issues normally
associated with producing new products.
The targeted
specific details
of the desired catalytic material,
including morphology and chemical and physical
properties, will need to be communicated to us by our client partners
so that we can know what value-added material to synthesize. At this
juncture we are attempting to identify synergies between Sawyer
Technical Materials and
prospective partners to illuminate the opportunity to
overcome catalytic material barriers.
Advantages
Several
advantages of Sawyer's hydrothermal materials synthesis technology
include:
- Low synthesis temperatures -
under 500°C, often < 200°C
- Low aggregation
and agglomeration
levels of powders.
- Excellent control of
crystallite size and morphology
- Unique defect structure,
different than in other high-temperature techniques
- High purity - hydrothermal
growth is a self-purifying process
- Scale-up issues practically
eliminated
- One-step processing with
limited or no required high-temperature annealing and/or
milling
Markets
Sawyer recognizes the
limitless possibilities that hydrothermal synthesis can deliver for
a variety of markets with its ability to dial-in specific materials
for configuration. The defining variable in the research process is
identifying a capability partner and encouraging them to ask the
question, "Can you make this material with these chemical and
physical properties, micro structures and morphologies?"
This simple question is the
catalyst in overcoming barriers and initiating solutions for a
myriad of market applications including (but not limited to):
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Chemical/Petrochemical
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Oil Refining
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Energy
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Pharmaceutical
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Cosmetic
Of course, the definition of
success is not always that obvious, so Sawyer offers a novel
approach to combinatorial studies utilizing industrial conditions.
Custom
Synthesis
Our
initial goal is to convey to potential client partners Sawyer's
expertise and success with our unique capabilities and synthesis
process and how we represent an opportunity to pursue the
development of products utilizing materials otherwise unknown or
unavailable to them. Once we've achieved this, we'll have our
prospects provide a group of targets that can be used and tested to
efficiently develop crystalline materials. Sawyer can then utilize
our hydrothermal synthesis expertise and capabilities in a variety
of different combinations to overcome existing barriers and achieve
novel materials.
Some key custom synthesis critical property values to consider:
- Surface Area
- Porosity
- Pore Size Distribution
- Crush Strength
- Phase Purity
- Chemical composition (including doping)
Once testing is enacted, our mutual goal is to overcome
barriers by identifying where improvement is viable to replace
an existing material; or creating a new material entirely within
our hydrothermal synthesis processes.
The following catalytic materials have also
been synthesized hydrothermally by Sawyer:
The above examples are by no means an exhaustive
list of our capabilities. We invite you to evaluate your past
and current materials challenges and identify applications where
a better or previously unavailable material could make a significant
difference in your business.
Download/Tech-Papers
Hydrothermal technology offers many advantages over conventional
and non-conventional synthesis methods of inorganic materials.
Attached is a technical paper on hydrothermal synthesis presented by our
R&D
Director – Ceramic Materials; please click to preview the complete
study: (Hydrothermal
Synthesis Study)
We are ready to discuss the feasibility of providing materials
to you consisting of the specific properties you provide. We also
realize that exact properties are not always known and that a
few to several iterations may be required. We would like to invite
you to visit our plant in Cleveland and participate in our technical
presentation whenever it is convenient for you.
Data Sheets
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a-alumina
whiskers |
View |
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AA
powders |
View |
| Coatings |
View |
| Corundum all sizes SEM+PSD final |
View |
| Nanosized AA powders |
View |
| Nanosized powders general |
View |
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Zinc
aluminate spinel powder |
View |
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Zinc
oxide nanosized powders |
View |
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Tech Briefs |
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Thin
films by Hydrothermal Epitaxy |
View |
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Hydrothermal synthesis of
nanosized ZnO powders |
View |
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Hydrothermal Synthesis of
a-alumina
& ceramic supports |
View |
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Hydrothermal Synthesis of
Materials-Review |
View |
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MSDS |
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